Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Martin Jarenmark; Hakan Carlsson; Vladimir Trukhan; Matti Haukka; Sophie Canton; Monica Walczak; Wilfred Fullagar; Villy Sundström; Ebbe Nordlander

doi:10.1016/j.inoche.2009.12.007

Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Martin Jarenmark, Hakan Carlsson, Vladimir Trukhan, Matti Haukka, Sophie Canton, Monica Walczak, Wilfred Fullagar, Villy Sundström, Ebbe Nordlander

Research output: Contribution to journal › Article › peer-review

Abstract

The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved

Original language	English
Pages (from-to)	334-337
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2009.12.007
Publication status	Published - 2010

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Transesterification
Model complexes
phosphatase
Purple acid
Dinuclear
Bioinorganic chemistry
Heterodinuclear
Zinc
Iron
HPNP

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10.1016/j.inoche.2009.12.007

Cite this

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title = "Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases",

abstract = "The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved",

keywords = "Transesterification, Model complexes, phosphatase, Purple acid, Dinuclear, Bioinorganic chemistry, Heterodinuclear, Zinc, Iron, HPNP",

author = "Martin Jarenmark and Hakan Carlsson and Vladimir Trukhan and Matti Haukka and Sophie Canton and Monica Walczak and Wilfred Fullagar and Villy Sundstr{\"o}m and Ebbe Nordlander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2010",

doi = "10.1016/j.inoche.2009.12.007",

language = "English",

volume = "13",

pages = "334--337",

journal = "Inorganic Chemistry Communications",

issn = "1879-0259",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

AU - Jarenmark, Martin

AU - Carlsson, Hakan

AU - Trukhan, Vladimir

AU - Haukka, Matti

AU - Canton, Sophie

AU - Walczak, Monica

AU - Fullagar, Wilfred

AU - Sundström, Villy

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2010

Y1 - 2010

N2 - The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved

AB - The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved

KW - Transesterification

KW - Model complexes

KW - phosphatase

KW - Purple acid

KW - Dinuclear

KW - Bioinorganic chemistry

KW - Heterodinuclear

KW - Zinc

KW - Iron

KW - HPNP

U2 - 10.1016/j.inoche.2009.12.007

DO - 10.1016/j.inoche.2009.12.007

M3 - Article

SN - 1879-0259

VL - 13

SP - 334

EP - 337

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

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