The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

George Kostakis; Pantelis Xydias; Ebbe Nordlander; John C. Plakatouras

doi:10.1016/j.ica.2011.10.063

The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

George Kostakis, Pantelis Xydias, Ebbe Nordlander, John C. Plakatouras

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.

Original language	English
Pages (from-to)	327-331
Journal	Inorganica Chimica Acta
Volume	383
DOIs	https://doi.org/10.1016/j.ica.2011.10.063
Publication status	Published - 2012

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Copper
3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1
2
[1-(4-((1H-benzo[d][1
3]triazole]
Complex
X-ray

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10.1016/j.ica.2011.10.063

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title = "The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]",

abstract = "The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.",

keywords = "Copper, 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2, [1-(4-((1H-benzo[d][1, 3]triazole], Complex, X-ray",

author = "George Kostakis and Pantelis Xydias and Ebbe Nordlander and Plakatouras, \{John C.\}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2012",

doi = "10.1016/j.ica.2011.10.063",

language = "English",

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T1 - The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

AU - Kostakis, George

AU - Xydias, Pantelis

AU - Nordlander, Ebbe

AU - Plakatouras, John C.

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2012

Y1 - 2012

N2 - The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.

AB - The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.

KW - Copper

KW - 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1

KW - 2

KW - [1-(4-((1H-benzo[d][1

KW - 3]triazole]

KW - Complex

KW - X-ray

UR - https://www.scopus.com/pages/publications/84857234259

U2 - 10.1016/j.ica.2011.10.063

DO - 10.1016/j.ica.2011.10.063

M3 - Article

SN - 0020-1693

VL - 383

SP - 327

EP - 331

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

Abstract

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