The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Jessica Nilsson; Stephen B. Colbran; Ulrich Behrens; Dieter Rehder; Ebbe Nordlander

doi:10.1016/j.ica.2012.04.041

The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Jessica Nilsson, Stephen B. Colbran, Ulrich Behrens, Dieter Rehder, Ebbe Nordlander

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.

Original language	English
Pages (from-to)	490-493
Journal	Inorganica Chimica Acta
Volume	392
DOIs	https://doi.org/10.1016/j.ica.2012.04.041
Publication status	Published - 2012

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Vanadium
Vanadyl cation
Reduction
Ascidians

Access to Document

10.1016/j.ica.2012.04.041

Cite this

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title = "The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine",

abstract = "Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.",

keywords = "Vanadium, Vanadyl cation, Reduction, Ascidians",

author = "Jessica Nilsson and Colbran, \{Stephen B.\} and Ulrich Behrens and Dieter Rehder and Ebbe Nordlander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

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doi = "10.1016/j.ica.2012.04.041",

language = "English",

volume = "392",

pages = "490--493",

journal = "Inorganica Chimica Acta",

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T1 - The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

AU - Nilsson, Jessica

AU - Colbran, Stephen B.

AU - Behrens, Ulrich

AU - Rehder, Dieter

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2012

Y1 - 2012

N2 - Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.

AB - Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.

KW - Vanadium

KW - Vanadyl cation

KW - Reduction

KW - Ascidians

UR - https://www.scopus.com/pages/publications/84865745221

U2 - 10.1016/j.ica.2012.04.041

DO - 10.1016/j.ica.2012.04.041

M3 - Article

SN - 0020-1693

VL - 392

SP - 490

EP - 493

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

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