The water dimer in a too tight matrix cage

Anders Engdahl; Bengt Nelander

doi:10.1039/b111588j

The water dimer in a too tight matrix cage

Anders Engdahl, Bengt Nelander

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.

Original language	English
Pages (from-to)	2140-2143
Journal	Physical Chemistry Chemical Physics
Volume	4
Issue number	11
DOIs	https://doi.org/10.1039/b111588j
Publication status	Published - 2002

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

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10.1039/b111588j

Cite this

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title = "The water dimer in a too tight matrix cage",

abstract = "When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.",

author = "Anders Engdahl and Bengt Nelander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2002",

doi = "10.1039/b111588j",

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journal = "Physical Chemistry Chemical Physics",

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publisher = "Royal Society of Chemistry",

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AU - Nelander, Bengt

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PY - 2002

Y1 - 2002

N2 - When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.

AB - When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.

U2 - 10.1039/b111588j

DO - 10.1039/b111588j

M3 - Article

SN - 1463-9084

VL - 4

SP - 2140

EP - 2143

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 11

ER -

The water dimer in a too tight matrix cage

Abstract

Bibliographical note

Subject classification (UKÄ)

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