The water-hydroxyl radical complex: A matrix isolation study.

Anders Engdahl; Gunnar Karlström; Bengt Nelander

doi:10.1063/1.1563608

The water-hydroxyl radical complex: A matrix isolation study.

Anders Engdahl, Gunnar Karlström, Bengt Nelander

Research output: Contribution to journal › Article › peer-review

Abstract

The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. ©2003 American Institute of Physics.

Original language	English
Pages (from-to)	7797-7802
Journal	Journal of Chemical Physics
Volume	118
Issue number	17
DOIs	https://doi.org/10.1063/1.1563608
Publication status	Published - 2003

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060), Theoretical Chemistry (S) (011001039), Max-laboratory (011012005)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics
Theoretical Chemistry

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10.1063/1.1563608

Cite this

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title = "The water-hydroxyl radical complex: A matrix isolation study.",

abstract = "The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. {\textcopyright}2003 American Institute of Physics.",

author = "Anders Engdahl and Gunnar Karlstr{\"o}m and Bengt Nelander",

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AU - Karlström, Gunnar

AU - Nelander, Bengt

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Y1 - 2003

N2 - The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. ©2003 American Institute of Physics.

AB - The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. ©2003 American Institute of Physics.

U2 - 10.1063/1.1563608

DO - 10.1063/1.1563608

M3 - Article

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VL - 118

SP - 7797

EP - 7802

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 17

ER -

The water-hydroxyl radical complex: A matrix isolation study.

Abstract

Bibliographical note

Subject classification (UKÄ)

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