Abstract
The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | M639-M640 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 58 |
| Issue number | part 11 |
| DOIs | |
| Publication status | Published - 2002 |
Bibliographical note
The information about affiliations in this record was updated in December 2015.The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Inorganic chemistry (ceased) (LUR000010)
Subject classification (UKÄ)
- Organic Chemistry