Unconjugated diimine palladium complexes as Heck coupling catalysts

Simphiwe M Nelana; Jezreel Cloete; George C Lisensky; Ebbe Nordlander; Ilia A Guzei; Selwyn F Mapolie; James Darkwa

doi:10.1016/j.molcata.2008.01.009

Unconjugated diimine palladium complexes as Heck coupling catalysts

Simphiwe M Nelana, Jezreel Cloete, George C Lisensky, Ebbe Nordlander, Ilia A Guzei, Selwyn F Mapolie, James Darkwa

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

Original language	English
Pages (from-to)	72-78
Journal	Journal of Molecular Catalysis A: Chemical
Volume	285
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2008.01.009
Publication status	Published - 2008

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Heck coupling catalysts
crystal structures
unconjugated diimine ligands
palladium complexes

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10.1016/j.molcata.2008.01.009

Cite this

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abstract = "Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.",

keywords = "Heck coupling catalysts, crystal structures, unconjugated diimine ligands, palladium complexes",

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note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

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doi = "10.1016/j.molcata.2008.01.009",

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T1 - Unconjugated diimine palladium complexes as Heck coupling catalysts

AU - Nelana, Simphiwe M

AU - Cloete, Jezreel

AU - Lisensky, George C

AU - Nordlander, Ebbe

AU - Guzei, Ilia A

AU - Mapolie, Selwyn F

AU - Darkwa, James

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2008

Y1 - 2008

N2 - Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

AB - Four unconjugated diimine palladium complexes have been synthesized, and spectroscopically and structurally characterized. All four palladium complexes were used as catalysts in the Heck coupling reaction between iodobenzene and methyl acrylate or butyl acrylate with very good conversion to either methyl (2E)-3-phenylacrylate or butyl (2E)-3-phenylacrylate.

KW - Heck coupling catalysts

KW - crystal structures

KW - unconjugated diimine ligands

KW - palladium complexes

UR - https://www.scopus.com/pages/publications/43049084714

U2 - 10.1016/j.molcata.2008.01.009

DO - 10.1016/j.molcata.2008.01.009

M3 - Article

SN - 1381-1169

VL - 285

SP - 72

EP - 78

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Unconjugated diimine palladium complexes as Heck coupling catalysts

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

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