Unprecedented enantioselectivity in a cluster-based catalytic system

Viktor Moberg; Matti Haukka; Igor Koshevoy; Roberto Ortiz; Ebbe Nordlander

doi:10.1021/om070211d

Unprecedented enantioselectivity in a cluster-based catalytic system

Viktor Moberg, Matti Haukka, Igor Koshevoy, Roberto Ortiz, Ebbe Nordlander

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Catalytic systems based on the clusters [H4RU4(CO)(10)-{mu-1,2-(P-P)}] and [H4RU4(CO)(10){1,1-(P-P)}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92% and conversion rates in excess of 99% were observed.

Original language	English
Pages (from-to)	4090-4093
Journal	Organometallics
Volume	26
Issue number	17
DOIs	https://doi.org/10.1021/om070211d
Publication status	Published - 2007

Subject classification (UKÄ)

Inorganic Chemistry

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10.1021/om070211d

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title = "Unprecedented enantioselectivity in a cluster-based catalytic system",

abstract = "Catalytic systems based on the clusters [H4RU4(CO)(10)-\{mu-1,2-(P-P)\}] and [H4RU4(CO)(10)\{1,1-(P-P)\}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92\% and conversion rates in excess of 99\% were observed.",

author = "Viktor Moberg and Matti Haukka and Igor Koshevoy and Roberto Ortiz and Ebbe Nordlander",

year = "2007",

doi = "10.1021/om070211d",

language = "English",

volume = "26",

pages = "4090--4093",

journal = "Organometallics",

issn = "1520-6041",

publisher = "The American Chemical Society (ACS)",

number = "17",

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T1 - Unprecedented enantioselectivity in a cluster-based catalytic system

AU - Moberg, Viktor

AU - Haukka, Matti

AU - Koshevoy, Igor

AU - Ortiz, Roberto

AU - Nordlander, Ebbe

PY - 2007

Y1 - 2007

N2 - Catalytic systems based on the clusters [H4RU4(CO)(10)-{mu-1,2-(P-P)}] and [H4RU4(CO)(10){1,1-(P-P)}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92% and conversion rates in excess of 99% were observed.

AB - Catalytic systems based on the clusters [H4RU4(CO)(10)-{mu-1,2-(P-P)}] and [H4RU4(CO)(10){1,1-(P-P)}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92% and conversion rates in excess of 99% were observed.

UR - https://www.scopus.com/pages/publications/34548178516

U2 - 10.1021/om070211d

DO - 10.1021/om070211d

M3 - Article

SN - 1520-6041

VL - 26

SP - 4090

EP - 4093

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Unprecedented enantioselectivity in a cluster-based catalytic system

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