Water-olefin complexes.: A matrix isolation study

Anders Engdahl; Bengt Nelander

doi:10.1021/j100412a023

Water-olefin complexes. A matrix isolation study

Anders Engdahl, Bengt Nelander

Faculty of Science

Research output: Contribution to journal › Article › peer-review

Abstract

The infrared spectra of the H₂O, HDO, and D₂O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.

Original language	English
Pages (from-to)	4982-4987
Number of pages	6
Journal	Journal of Physical Chemistry
Volume	90
Issue number	21
DOIs	https://doi.org/10.1021/j100412a023
Publication status	Published - 1986

Bibliographical note

Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.

Subject classification (UKÄ)

Atom and Molecular Physics and Optics
Physical Chemistry (including Surface- and Colloid Chemistry)

Access to Document

10.1021/j100412a023

Cite this

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title = "Water-olefin complexes.: A matrix isolation study",

abstract = "The infrared spectra of the H2O, HDO, and D2O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.",

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year = "1986",

doi = "10.1021/j100412a023",

language = "English",

volume = "90",

pages = "4982--4987",

journal = "Journal of Physical Chemistry",

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publisher = "The American Chemical Society (ACS)",

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T1 - Water-olefin complexes.

T2 - A matrix isolation study

AU - Engdahl, Anders

AU - Nelander, Bengt

PY - 1986

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AB - The infrared spectra of the H2O, HDO, and D2O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.

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