Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework

Biswanath Das; Bao Lin Lee; Erik A. Karlsson; Torbjörn Åkermark; Andrey Shatskiy; Serhiy Demeshko; Rong-Zhen Liao; Tanja M. Laine; Matti Haukka; Erica Zeglio; Ahmed F. Abdel-Magied; Per E M Siegbahn; Franc Meyer; Markus D. Kärkäs; Eric V. Johnston; Ebbe Nordlander; Björn Åkermark

doi:10.1039/c6dt01554a

Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework

Biswanath Das, Bao Lin Lee, Erik A. Karlsson, Torbjörn Åkermark, Andrey Shatskiy, Serhiy Demeshko, Rong-Zhen Liao, Tanja M. Laine, Matti Haukka, Erica Zeglio, Ahmed F. Abdel-Magied, Per E M Siegbahn, Franc Meyer, Markus D. Kärkäs, Eric V. Johnston, Ebbe Nordlander, Björn Åkermark

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the oneelectron oxidant [Ru(bpy)₃]³⁺.

Original language	English
Pages (from-to)	13289-13293
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	34
DOIs	https://doi.org/10.1039/c6dt01554a
Publication status	Published - 2016

Subject classification (UKÄ)

Inorganic Chemistry

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10.1039/c6dt01554a

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Das, B., Lee, B. L., Karlsson, E. A., Åkermark, T., Shatskiy, A., Demeshko, S., Liao, R.-Z., Laine, T. M., Haukka, M., Zeglio, E., Abdel-Magied, A. F., Siegbahn, P. E. M., Meyer, F., Kärkäs, M. D., Johnston, E. V., Nordlander, E., & Åkermark, B. (2016). Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework. Dalton Transactions, 45(34), 13289-13293. https://doi.org/10.1039/c6dt01554a

@article{f6d1f792867540dc8a67a480611b2485,

title = "Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework",

abstract = "The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the oneelectron oxidant [Ru(bpy)3]3+.",

author = "Biswanath Das and Lee, \{Bao Lin\} and Karlsson, \{Erik A.\} and Torbj{\"o}rn {\AA}kermark and Andrey Shatskiy and Serhiy Demeshko and Rong-Zhen Liao and Laine, \{Tanja M.\} and Matti Haukka and Erica Zeglio and Abdel-Magied, \{Ahmed F.\} and Siegbahn, \{Per E M\} and Franc Meyer and K{\"a}rk{\"a}s, \{Markus D.\} and Johnston, \{Eric V.\} and Ebbe Nordlander and Bj{\"o}rn {\AA}kermark",

year = "2016",

doi = "10.1039/c6dt01554a",

language = "English",

volume = "45",

pages = "13289--13293",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "34",

}

Das, B, Lee, BL, Karlsson, EA, Åkermark, T, Shatskiy, A, Demeshko, S, Liao, R-Z, Laine, TM, Haukka, M, Zeglio, E, Abdel-Magied, AF, Siegbahn, PEM, Meyer, F, Kärkäs, MD, Johnston, EV, Nordlander, E & Åkermark, B 2016, 'Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework', Dalton Transactions, vol. 45, no. 34, pp. 13289-13293. https://doi.org/10.1039/c6dt01554a

TY - JOUR

T1 - Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes

T2 - Importance of a proper ligand framework

AU - Das, Biswanath

AU - Lee, Bao Lin

AU - Karlsson, Erik A.

AU - Åkermark, Torbjörn

AU - Shatskiy, Andrey

AU - Demeshko, Serhiy

AU - Liao, Rong-Zhen

AU - Laine, Tanja M.

AU - Haukka, Matti

AU - Zeglio, Erica

AU - Abdel-Magied, Ahmed F.

AU - Siegbahn, Per E M

AU - Meyer, Franc

AU - Kärkäs, Markus D.

AU - Johnston, Eric V.

AU - Nordlander, Ebbe

AU - Åkermark, Björn

PY - 2016

Y1 - 2016

N2 - The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the oneelectron oxidant [Ru(bpy)3]3+.

AB - The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the oneelectron oxidant [Ru(bpy)3]3+.

UR - https://www.scopus.com/pages/publications/84983638449

U2 - 10.1039/c6dt01554a

DO - 10.1039/c6dt01554a

M3 - Article

C2 - 27265239

AN - SCOPUS:84983638449

SN - 1477-9226

VL - 45

SP - 13289

EP - 13293

JO - Dalton Transactions

JF - Dalton Transactions

IS - 34

ER -

Water oxidation catalyzed by molecular Di- and nonanuclear Fe complexes: Importance of a proper ligand framework

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