Abstract
We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.
| Original language | English |
|---|---|
| Journal | Physical Review E (Statistical, Nonlinear, and Soft Matter Physics) |
| Volume | 78 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2008 |
Bibliographical note
The information about affiliations in this record was updated in December 2015.The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
Subject classification (UKÄ)
- Theoretical Chemistry (including Computational Chemistry)
Free keywords
- Monte Carlo methods
- liquid theory
- electric fields
- electrochemistry
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