{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate

Research output: Contribution to journalArticle

Abstract

The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

Details

Authors
  • Lara C. Spencer
  • Haris Bjelosevic
  • James Darkwa
  • Sofi Elmroth
  • Tina Persson
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Organic Chemistry
  • Biological Sciences

Keywords

  • platinum, dppf, X-ray, ferrocene, single-crystal, Pt
Original languageEnglish
Pages (from-to)M164-U1562
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number1
Publication statusPublished - 2008
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Biochemistry and Structural Biology (S) (000006142)

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Related research output

Bjelosevic, H., 2008, Haris Bjelosevic, Organic Chemistry, Lund University. 85 p.

Research output: ThesisDoctoral Thesis (compilation)

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