Adsorption of ammonia on multilayer iron phthalocyanine.

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Abstract

The adsorption of ammonia on multilayers of well-ordered, flat-lying iron phthalocyanine (FePc) molecules on a Au(111) support was investigated by x-ray photoelectron spectroscopy. We find that the electron-donating ammonia molecules coordinate to the metal centers of iron phthlalocyanine. The coordination of ammonia induces changes of the electronic structure of the iron phthalocyanine layer, which, in particular, lead to a modification of the FePc valence electron spin.

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  • Natural Sciences
  • Atom and Molecular Physics and Optics
  • Physical Sciences
Original languageEnglish
Article number114711
JournalJournal of Chemical Physics
Volume134
Issue number11
Publication statusPublished - 2011
Publication categoryResearch
Peer-reviewedYes

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