Adsorption Studies of p-Aminobenzoic Acid on the Anatase TiO2(101) Surface

Research output: Contribution to journalArticle

Abstract

The adsorption of p-aminobenzoic acid (pABA) on the anatase TiO2(101) surface has been investigated using synchrotron radiation photoelectron spectroscopy, near edge X-ray absorption fine structure (NEXAFS) spectroscopy, and density functional theory (DFT). Photoelectron spectroscopy indicates that the molecule is adsorbed in a bidentate mode through the carboxyl group following deprotonation. NEXAFS spectroscopy and DFT calculations of the adsorption structures indicate the ordering of a monolayer of the amino acid on the surface with the plane of the ring in an almost upright orientation. The adsorption of pABA on nanoparticulate TiO2 leads to a red shift of the optical absorption relative to bare TiO2 nanoparticles. DFT and valence band photoelectron spectroscopy suggest that the shift is attributed to the presence of the highest occupied molecular orbitals in the TiO2 band gap region and the presence of new molecularly derived states near the foot of the TiO2 conduction band.

Details

Authors
  • Andrew G. Thomas
  • Mark J. Jackman
  • Michael Wagstaffe
  • Hanna Radtke
  • Karen Syres
  • Johan Adell
  • Anna Levy
  • Natalia Martsinovich
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Physical Sciences
  • Natural Sciences
Original languageEnglish
Pages (from-to)12306-12314
JournalLangmuir
Volume30
Issue number41
Publication statusPublished - 2014
Publication categoryResearch
Peer-reviewedYes