Balancing power density based quantum yield characterization of upconverting nanoparticles for arbitrary excitation intensities.

Research output: Contribution to journalArticle

Abstract

Upconverting nanoparticles (UCNPs) have recently shown great potential as contrast agents in biological applications. In developing different UCNPs, the characterization of their quantum yield (QY) is a crucial issue, as the typically drastic decrease in QY for low excitation power densities can either impose a severe limitation or provide an opportunity in many applications. The power density dependence of the QY is governed by the competition between the energy transfer upconversion (ETU) rate and the linear decay rate in the depopulation of the intermediate state of the involved activator in the upconversion process. Here we show that the QYs of Yb(3+) sensitized two-photon upconversion emissions can be well characterized by the balancing power density, at which the ETU rate and the linear decay rate have equal contributions, and its corresponding QY. The results in this paper provide a method to fully describe the QY of upconverting nanoparticles for arbitrary excitation power densities, and is a fast and simple approach for assessing the applicability of UCNPs from the perspective of energy conversion.

Details

Authors
  • Haichun Liu
  • Can Xu
  • David Lindgren
  • Haiyan Xie
  • Diana Thomas
  • Carsten Gundlach
  • Stefan Andersson-Engels
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Nano Technology
Original languageEnglish
Pages (from-to)4770-4775
JournalNanoscale
Volume5
Issue number11
Publication statusPublished - 2013
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

Department affilation moved from v1000583 (Molecular Tumour Biology) to v1000562 (Department of Translational Medicine) on 2016-01-18 14:41:47.

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