Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization

Research output: Contribution to journalArticle

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Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization. / Karpenko, A.; Iablonskyi, D.; Urpelainen, Samuli; Kettunen, J. A.; Cao, W.; Huttula, M.; Aksela, H.

In: Journal of Chemical Physics, Vol. 140, No. 20, 204321, 2014.

Research output: Contribution to journalArticle

Harvard

Karpenko, A, Iablonskyi, D, Urpelainen, S, Kettunen, JA, Cao, W, Huttula, M & Aksela, H 2014, 'Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization', Journal of Chemical Physics, vol. 140, no. 20, 204321. https://doi.org/10.1063/1.4880120

APA

Karpenko, A., Iablonskyi, D., Urpelainen, S., Kettunen, J. A., Cao, W., Huttula, M., & Aksela, H. (2014). Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization. Journal of Chemical Physics, 140(20), [204321]. https://doi.org/10.1063/1.4880120

CBE

Karpenko A, Iablonskyi D, Urpelainen S, Kettunen JA, Cao W, Huttula M, Aksela H. 2014. Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization. Journal of Chemical Physics. 140(20). https://doi.org/10.1063/1.4880120

MLA

Vancouver

Karpenko A, Iablonskyi D, Urpelainen S, Kettunen JA, Cao W, Huttula M et al. Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization. Journal of Chemical Physics. 2014;140(20). 204321. https://doi.org/10.1063/1.4880120

Author

Karpenko, A. ; Iablonskyi, D. ; Urpelainen, Samuli ; Kettunen, J. A. ; Cao, W. ; Huttula, M. ; Aksela, H. / Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization. In: Journal of Chemical Physics. 2014 ; Vol. 140, No. 20.

RIS

TY - JOUR

T1 - Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization

AU - Karpenko, A.

AU - Iablonskyi, D.

AU - Urpelainen, Samuli

AU - Kettunen, J. A.

AU - Cao, W.

AU - Huttula, M.

AU - Aksela, H.

PY - 2014

Y1 - 2014

N2 - The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr. (C) 2014 AIP Publishing LLC.

AB - The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr. (C) 2014 AIP Publishing LLC.

U2 - 10.1063/1.4880120

DO - 10.1063/1.4880120

M3 - Article

VL - 140

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 20

M1 - 204321

ER -