Diastereoselective formation of 2,3,4,5-tetrasubstituted tetrahydrofurans by a Lewis acid promoted addition of C3-substituted 1,3-bis(silyl)propenes to aldehydes

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Abstract

A mild, efficient, Lewis acid promoted addition of C3-substituted 1,3-bis(silyl)propenes to aldehydes to provide the corresponding 2,3,4,5-tetrasubstituted tetrahydrofurans in excellent stereoselectivity is reported. (C) 2013 Elsevier Ltd. All rights reserved.

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Subject classification (UKÄ) – MANDATORY

  • Chemical Sciences

Keywords

  • Tetrahydrofuran, Allylsilanes, Diastereoselectivity, Lewis acid, Aldehyde
Original languageEnglish
Pages (from-to)3916-3918
JournalTetrahedron Letters
Volume54
Issue number30
Publication statusPublished - 2013
Publication categoryResearch
Peer-reviewedYes