Electron spectroscopy study of the initial stages of iron phthalocyanine growth on highly oriented pyrolitic graphite.

Research output: Contribution to journalArticle

Abstract

The nature of the intermolecular and substrate bonds of iron phthalocyanine adsorbed on highly oriented pyrolitic graphite has been investigated by x-ray photoelectron spectroscopy and x-ray absorption spectroscopy. We find that the molecules grow in a highly ordered fashion with the molecules essentially plane-parallel to the surface in both the mono- and multilayers. The spectra obtained on both types of film are virtually identical, which shows that the bonds both between the adsorbate and substrate and between the molecular layers have a pure van der Waals nature. Supporting density functional theory results indicate that the layers are stabilized by weak hydrogen bonds within the molecular layers.

Details

Authors
  • Cristina Isvoranu
  • John Ahlund
  • Bin Wang
  • Evren Ataman
  • Nils Mårtensson
  • Carla Puglia
  • Jesper N Andersen
  • Marie-Laure Bocquet
  • Joachim Schnadt
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Natural Sciences
  • Atom and Molecular Physics and Optics
  • Physical Sciences
Original languageEnglish
Article number214709
JournalJournal of Chemical Physics
Volume131
Issue number21
Publication statusPublished - 2009
Publication categoryResearch
Peer-reviewedYes