Fuel cell evaluation of anion exchange membranes based on poly(phenylene oxide) with different cationic group placement

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Abstract

Four novel poly(phenylene oxide)-based anion exchange membranes were investigated for electrochemical performance, ionic conductivity and water transport properties in an operating anion exchange membrane fuel cell (AEMFC) , using Pt/C gas diffusion electrodes with Tokuyama ionomer. The poly(phenylene oxide)-membranes have a 1- or 5-carbon alkyl spacer between the backbone and a trimethylalkylammonium (TMA) or piperidinium (Pip) cationic group, and ion-exchange capacities (IECs) between 1.5 and 1.9 mequiv g-1. The polymer with a 5-carbon alkyl spacer, a TMA cationic group, and a higher IEC showed the highest ion conductivity and performance in the AEMFC. The results also show that introducing a 5-carbon alkyl spacer does not improve performance unless the IEC is increased and that exchanging the TMA with a Pip cationic group results in lower fuel cell performance despite a higher IEC. A discrepancy in ion conductivity between fuel cell and ex-situ test was observed for the 5-carbon spacer polymers and is attributed to a higher sensitivity for dehydration. Similar water flux under load, from the anode to the cathode with increased water content at both electrodes, was observed for all membranes and only varied with membrane thickness. The deviation in fuel cell performance observed between the membranes could not be explained by differences in water flux or ionic conduction, suggesting that the electrodes – membrane interaction plays a major role. Nevertheless, the study emphasizes that high membrane conductivity (for the λ-range in a fuel cell) and an efficient water transport (obtained by lower membrane thickness) promote higher electrochemical performance.
Annika Carlson,   Björn Eriksson,   Joel S Olsson,   Göran Lindbergh,   Carina Lagergren,   Patric Jannasch  and  Rakel Wreland-Lindström  

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External organisations
  • KTH Royal Institute of Technology
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Polymer Technologies
  • Polymer Chemistry
  • Energy Systems
  • Materials Chemistry
Original languageEnglish
JournalSustainable Energy & Fuels
Publication statusPublished - 2020
Publication categoryResearch
Peer-reviewedYes