High resolution X-ray emission spectroscopy of liquid water: The observation of two structural motifs

Research output: Contribution to journalArticle

Abstract

The structure of liquid water is presently under intense debate. We summarize the historical development of the present description of water and the controversy surrounding the X-ray absorption spectroscopy (XAS) study of Wernet et al. [Ph. Wernet et al., Science 304 (2004) 995]. In order to provide further insight into the connection between X-ray spectroscopy and the structure of the hydrogen bonding network, we report new data comprising high resolution oxygen K-edge X-ray emission spectra (XES) of liquid water. We observe two distinct narrow lone-pair derived peaks, assigned, respectively, to tetrahedral and strongly distorted hydrogen-bonded species; the assignment is based on comparison with ice and gas phase spectra, temperature dependent measurements, excitation energy dependence and theoretical simulations. We estimate a 2:1 ratio between distorted and tetrahedral species at room temperature and discuss what this implies in connection to the previous XAS study and in terms of liquid water structure.

Details

Authors
  • T. Tokushima
  • Y. Harada
  • O. Takahashi
  • Y. Senba
  • H. Ohashi
  • Lars G.M. Pettersson
  • Anders Nilsson
  • S. Shin
External organisations
  • RIKEN SPring-8 center
  • Hiroshima University
  • Stockholm University
  • Stanford Linear Accelerator Center (SLAC)
  • University of Tokyo
Original languageEnglish
Pages (from-to)387-400
Number of pages14
JournalChemical Physics Letters
Volume460
Issue number4-6
Publication statusPublished - 2008 Jul 30
Publication categoryResearch
Peer-reviewedYes
Externally publishedYes