High-Resolution Infrared and Microwave Study of the n20 and n21 Levels near 300 cm-1 in 1,2,4-Triazine.

Research output: Contribution to journalArticle

Abstract

The gas phase far-IR spectrum of the small nu, Greek20 (A″, 367.88 cm−1) and small nu, Greek21 (A″, 311.28 cm−1) bands of 1,2,4-triazine, a five membered ring having the point group Cs, has been studied at a resolution ranging from 0.002 to 0.003 cm−1. From the MW spectrum 58 transitions in the small nu, Greek20 level and 64 in the small nu, Greek21 level have been assigned. The small nu, Greek20 and small nu, Greek21 modes which are due to non-planar motions of the ring system are found to be nearly unperturbed. From a simultaneous analysis of IR and MW transitions band centers, rotational constants, and the quartic centrifugal distortion constants ΔJ, ΔJK, ΔK, small delta, GreekJ, and small delta, GreekK have been obtained using the Watson Hamiltonian, A-reduction, IIIr-representation.

Details

Authors
  • F Hegelund
  • René Wugt Larsen
  • Bengt Nelander
  • D. Christen
  • M.H. Palmer
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Atom and Molecular Physics and Optics

Keywords

  • 1, 2, 4-Triazine, Infrared, Microwave, Rotational constants
Original languageEnglish
Pages (from-to)9-18
JournalJournal of Molecular Spectroscopy
Volume217
Issue number1
Publication statusPublished - 2003
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060), Max-laboratory (011012005)