Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction
Research output: Contribution to journal › Article
Abstract
The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.
Details
| Authors | |
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| Organisations | |
| Research areas and keywords | Subject classification (UKÄ) – MANDATORY
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| Original language | English |
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| Pages (from-to) | 1583-1590 |
| Journal | Organometallics |
| Volume | 21 |
| Issue number | 8 |
| Publication status | Published - 2002 |
| Publication category | Research |
| Peer-reviewed | Yes |
Bibliographic note
The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
