Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction

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Abstract

The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.

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  • Organic Chemistry
Original languageEnglish
Pages (from-to)1583-1590
JournalOrganometallics
Volume21
Issue number8
Publication statusPublished - 2002
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)