Kinetics of the gas‐phase reactions of chlorine atoms with CH²F², CH³CCl³, and CF³CFH² over the temperature range 253–553 K

Research output: Contribution to journalArticle

Abstract

Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10−17 T2 exp(−1023/T) cm3 molecule−1 s−1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10−12 exp(−1630/T) cm3 molecule−1 s−1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10−12 exp(−2019/T) cm3 molecule−1 s−1 (253–313 K). Results are discussed with respect to the literature data.

Details

Authors
External organisations
  • University of Copenhagen
  • University of Michigan-Dearborn
  • Ford Motor
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Organic Chemistry
Original languageEnglish
Pages (from-to)401-406
Number of pages6
JournalInternational Journal of Chemical Kinetics
Volume41
Issue number6
Publication statusPublished - 2009 Jun 1
Publication categoryResearch
Peer-reviewedYes
Externally publishedYes