Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum

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Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum. / Richter, J. H.; Karlsson, P. G.; Westin, G.; Blomquist, Jakob; Uvdal, Per; Siegbahn, H.; Sandell, A.

In: Journal of Physical Chemistry C, Vol. 111, No. 8, 2007, p. 3459-3466.

Research output: Contribution to journalArticle

Harvard

Richter, JH, Karlsson, PG, Westin, G, Blomquist, J, Uvdal, P, Siegbahn, H & Sandell, A 2007, 'Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum', Journal of Physical Chemistry C, vol. 111, no. 8, pp. 3459-3466. https://doi.org/10.1021/jp066192n

APA

Richter, J. H., Karlsson, P. G., Westin, G., Blomquist, J., Uvdal, P., Siegbahn, H., & Sandell, A. (2007). Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum. Journal of Physical Chemistry C, 111(8), 3459-3466. https://doi.org/10.1021/jp066192n

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MLA

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Author

Richter, J. H. ; Karlsson, P. G. ; Westin, G. ; Blomquist, Jakob ; Uvdal, Per ; Siegbahn, H. ; Sandell, A. / Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum. In: Journal of Physical Chemistry C. 2007 ; Vol. 111, No. 8. pp. 3459-3466.

RIS

TY - JOUR

T1 - Li insertion in sol-gel prepared Mn-doped TiO2 studied by electron spectroscopy in ultrahigh vacuum

AU - Richter, J. H.

AU - Karlsson, P. G.

AU - Westin, G.

AU - Blomquist, Jakob

AU - Uvdal, Per

AU - Siegbahn, H.

AU - Sandell, A.

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2007

Y1 - 2007

N2 - The properties of a sol-gel prepared Mn-modified TiO2 film have been studied with X-ray absorption spectroscopy (XAS) and photoelectron spectroscopy (PES) using synchrotron radiation. The chemical composition and oxidation state of the elements have been determined. The manganese content estimated by PES of the Mn-modified film is about 10% and both Mn2+ and Mn3+ are observed. Addition of Mn is found to modify the valence band edge. The Mn 3d states are found to extend about 1 eV into the TiO2 band gap region. It is demonstrated that lithium insertion into the sol-gel film can be performed in a stepwise fashion in situ under ultrahigh vacuum (UHV) conditions. Lithium is distributed evenly throughout the entire film and leads to reduction of Mn3+ to Mn2+ followed by reduction of Ti4+ to Ti3+. The XAS and PES measurements give fully consistent results regarding the amount of inserted lithium.

AB - The properties of a sol-gel prepared Mn-modified TiO2 film have been studied with X-ray absorption spectroscopy (XAS) and photoelectron spectroscopy (PES) using synchrotron radiation. The chemical composition and oxidation state of the elements have been determined. The manganese content estimated by PES of the Mn-modified film is about 10% and both Mn2+ and Mn3+ are observed. Addition of Mn is found to modify the valence band edge. The Mn 3d states are found to extend about 1 eV into the TiO2 band gap region. It is demonstrated that lithium insertion into the sol-gel film can be performed in a stepwise fashion in situ under ultrahigh vacuum (UHV) conditions. Lithium is distributed evenly throughout the entire film and leads to reduction of Mn3+ to Mn2+ followed by reduction of Ti4+ to Ti3+. The XAS and PES measurements give fully consistent results regarding the amount of inserted lithium.

U2 - 10.1021/jp066192n

DO - 10.1021/jp066192n

M3 - Article

VL - 111

SP - 3459

EP - 3466

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 8

ER -