Multicomponent Interdiffusion and Self-Diffusion of the Cationic Poly{[9,9-bis(6 '-N,N,N-trimethylammonium)hexyl]fluorene-phenylene} Dibromide in a Dimethyl Sulfoxide plus Water Solution

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Abstract

The diffusion behavior of the conjugated polyelectrolyte poly{[9,9-bis(6'-N,N,N-trimethylammonium)hexyl]fluorene-phenylene) bromide (HTMA-PFP) with different molecular weights has been studied in dimethyl sulfoxide (DMSO) + water solutions. Samples of HTMA-PFP with various molecular weights were obtained by synthesis of poly[9,9-bis(6'-bromohexyl)fluorene-phenylene] via a Suzuki coupling reaction, characterized by size exclusion chromatography (SEC), and quaternized with trimethylamine. Multicomponent chemical interdiffusion coefficients (mutual diffusion coefficients) were determined for solutions of HTMA-PFP and DMSO in water using the Taylor dispersion method. The results suggest specific interactions between the DMSO and the polymer. In addition, these systems were studied by pulse-field gradient nuclear magnetic resonance spectroscopy (PFG-NMR), and the corresponding self-diffusion coefficients were obtained. These were modeled using the Kirkwood-Riseman model, and a good fit to the observed behavior was obtained using literature data for molecular dimensions.

Details

Authors
  • Maria Monteserin
  • Maria J. Tapia
  • Ana C. F. Ribeiro
  • Cecilia I. A. V. Santos
  • Artur J. M. Valente
  • Hugh D. Burrows
  • Ricardo Mallavia
  • Markus Nilsson
  • Olle Söderman
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Physical Chemistry
Original languageEnglish
Pages (from-to)1860-1866
JournalJournal of Chemical and Engineering Data
Volume55
Issue number5
Publication statusPublished - 2010
Publication categoryResearch
Peer-reviewedYes