Near-infrared transmission spectroscopy of aqueous solutions: Influence of optical pathlength on signal-to-noise ratio

Research output: Contribution to journalArticle

Abstract

The optimal choice of optical pathlength, source intensity, and detector for near-infrared transmission measurements of trace components in aqueous solutions depends on the strong absorption of water. In this study we examine under which experimental circumstances one may increase the pathlength to obtain a measurement with higher signal-to-noise ratio. The noise level of measurements at eight different pathlengths from 0.2 to 2.0 mm of pure water and of 1 g/dL aqueous glucose signals were measured using a Fourier transform near-infrared spectrometer and a variable pathlength transmission cell. The measurements demonstrate that the noise level is determined by the water transmittance. The noise levels in the spectral region from 5000 to 4000 cm(-1) show that the optimal pathlength (0.4 mm) is the same for pure water and 1 g/dL aqueous glucose solutions. When detector saturation occurs it is favorable to increase the pathlength instead of attenuating the light source. The obtained results are explained by an analytical model.

Details

Authors
  • Peter Snoer Jensen
  • J Bak
Organisations
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Atom and Molecular Physics and Optics

Keywords

  • transmission, near-infrared spectroscopy, instrument configuration, optimal pathlength, FT-NIR, detector saturation, scattering
Original languageEnglish
Pages (from-to)1600-1606
JournalApplied Spectroscopy
Volume56
Issue number12
Publication statusPublished - 2002
Publication categoryResearch
Peer-reviewedYes

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Related research output

Snoer Jensen, P., 2003, Department of Physics, Lund University. 96 p.

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