Optimization of U and Pu traces separation by chromatography for analytical purposes: influence of U/Pu mass ratio

Research output: Contribution to journalArticle

Abstract

A study related to the separations of uranium traces in a concentrated Pu solution and plutonium traces in a concentrated U solution was performed (with Pu/U or U/Pu = 102–105). Its objective was to determine the U–Pu separation performances for a low U and Pu concentration range, namely: Pu solutions of 2.5 mg L−1 to 2.5 g L−1 containing traces of U (25 µg L−1), U solutions of 10 µg L−1 to 10 mg L−1 containing traces of Pu (100 ng L−1). The developed methods proved to be efficient and its robustness was confirmed with the treatment of high-activity real samples.

Details

Authors
External organisations
  • French Alternative Energies and Atomic Energy Commission (CEA)
Research areas and keywords

Keywords

  • Chromatography, Plutonium traces, Pu valency adjustment, Separations, Uranium traces
Original languageEnglish
Pages (from-to)1253-1261
Number of pages9
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume317
Issue number3
Publication statusPublished - 2018 Sep 1
Publication categoryResearch
Peer-reviewedYes
Externally publishedYes