Reactivity of carbon dioxide toward zirconocene cations

Research output: Contribution to journalArticle

Abstract

Cationic methyl- and phenylzirconocene species readily undergo insertion of CO2 into the zirconium-carbon bond, giving the corresponding dimeric carboxylato complexes 12 and 13 in quantitative yield. 12 was structurally characterized, displaying a bridging acetate ligand.

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Subject classification (UKÄ) – MANDATORY

  • Organic Chemistry
Original languageEnglish
Pages (from-to)5772-5775
JournalOrganometallics
Volume24
Issue number23
Publication statusPublished - 2005
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)