Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

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Abstract

The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].

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Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Physical Chemistry

Keywords

  • Cluster, Hemilabile ligand, Allylphosphine
Original languageEnglish
Pages (from-to)443-446
JournalInorganic Chemistry Communications
Volume7
Issue number3
Publication statusPublished - 2004
Publication categoryResearch
Peer-reviewedYes