Small ester combustion chemistry: Computational kinetics and experimental study of methyl acetate and ethyl acetate

Research output: Contribution to journalArticle

Abstract

Small esters represent an important class of high octane biofuels for advanced spark ignition engines. They qualify for stringent fuel screening standards and could be synthesized through various pathways. In this work, we performed a detailed investigation of the combustion of two small esters, MA (methyl acetate) and EA (ethyl acetate), including quantum chemistry calculations, experimental studies of combustion characteristics and kinetic model development. The quantum chemistry calculations were performed to obtain rates for H-atom abstraction reactions involved in the oxidation chemistry of these fuels. The series of experiments include: a shock tube study to measure ignition delays at 15 and 30 bar, 1000-1450 K and equivalence ratios of 0.5, 1.0 and 2.0; laminar burning velocity measurements in a heat flux burner over a range of equivalence ratios [0.7-1.4] at atmospheric pressure and temperatures of 298 and 338 K; and speciation measurements during oxidation in a jet-stirred reactor at 800-1100 K for MA and 650-1000 K for EA at equivalence ratios of 0.5, 1.0 and at atmospheric pressure. The developed chemical kinetic mechanism for MA and EA incorporates reaction rates and pathways from recent studies along with rates calculated in this work. The new mechanism shows generally good agreement in predicting experimental data across the broad range of experimental conditions. The experimental data, along with the developed kinetic model, provides a solid groundwork towards improving the understanding the combustion chemistry of smaller esters.

Details

Authors
  • Ahfaz Ahmed
  • William J. Pitz
  • Carlo Cavallotti
  • Marco Mehl
  • Nitin Lokachari
  • Elna J.K. Nilsson
  • Jui Yang Wang
  • Alexander A. Konnov
  • Scott W. Wagnon
  • Bingjie Chen
  • Zhandong Wang
  • Seonah Kim
  • Henry J. Curran
  • Stephen J. Klippenstein
  • William L. Roberts
  • S. Mani Sarathy
Organisations
External organisations
  • King Abdullah University of Science and Technology
  • Lawrence Livermore National Laboratory
  • Polytechnic University of Milan
  • National University of Ireland Galway
  • Argonne National Laboratory
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Energy Engineering

Keywords

  • Esters, Ignition, Jet Stirred Reactor, Kinetic mechanism, Laminar burning velocity
Original languageEnglish
Pages (from-to)419-428
JournalProceedings of the Combustion Institute
Volume37
Issue number1
Early online date2018 Jul 17
Publication statusPublished - 2019
Publication categoryResearch
Peer-reviewedYes