Synthesis of Formylsilanes through Oxidative Cleavage of α-Silyl Glycols.

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Abstract

A convenient method for the synthesis and isolation of highly reactive formylsilanes by oxidative cleavage of α-silyl glycols is presented. The mild conditions provide an entry to acid- and heat-sensitive members of this theoretically intriguing class of compounds. The utility of the method is demonstrated through the isolation and subsequent diastereoselective derivatization of t-BuMe2- and t-BuPh2-formylsilanes, previously not reported in isolated form.

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  • Chemical Sciences
Original languageEnglish
Pages (from-to)12268-12273
JournalJournal of Organic Chemistry
Volume78
Issue number23
Publication statusPublished - 2013
Publication categoryResearch
Peer-reviewedYes