The Role of Oxides in Catalytic CO Oxidation over Rhodium and Palladium

Research output: Contribution to journalArticle

Abstract

Catalytic CO oxidation is a seemingly simple reaction between CO and O2 molecules, one of the reactions in automotive catalytic converters, and the fruit-fly reaction in model catalysis. Surprisingly, the phase responsible for the catalytic activity is still under debate, despite decades of investigations. We have performed a simple but yet conclusive study of single crystal Rh and Pd model catalysts, resolving this controversy. For Rh, the oxygen-covered metallic surface is more active than the oxide, while for Pd, thin oxide films are at least as active as the metallic surface, but a thicker oxide is less active. Apart from resolving a long-standing debate, our results pinpoint important design principles for oxidation catalysts as to prevent catalytic extinction at high oxygen exposures.

Details

Authors
Organisations
External organisations
  • Stockholm University
  • Chalmers University of Technology
  • European Synchrotron Radiation Facility
  • Lawrence Berkeley National Laboratory
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Physical Chemistry

Keywords

  • active phase, CO oxidation, oxidation catalysis, oxide, palladium, rhodium, surface oxide
Original languageEnglish
Pages (from-to)4438-4445
Number of pages8
JournalACS Catalysis
Volume8
Issue number5
Publication statusPublished - 2018 May 4
Publication categoryResearch
Peer-reviewedYes