Three-Dimensional Printing of Bisphenol A-Free Polycarbonates

Research output: Contribution to journalArticle

Abstract

Polycarbonates are widely used in food packages, drink bottles, and various healthcare products such as dental sealants and tooth coatings. However, bisphenol A (BPA) and phosgene used in the production of commercial polycarbonates pose major concerns to public health safety. Here, we report a green pathway to prepare BPA-free polycarbonates (BFPs) by thermal ring-opening polymerization and photopolymerization. Polycarbonates prepared from two cyclic carbonates in different mole ratios demonstrated tunable mechanical stiffness, excellent thermal stability, and high optical transparency. Three-dimensional (3D) printing of the new BFPs was demonstrated using a two-photon laser direct writing system and a rapid 3D optical projection printer to produce structures possessing complex high-resolution geometries. Seeded C3H10T1/2 cells also showed over 95% viability with potential applications in biological studies. By combining biocompatible BFPs with 3D printing, novel safe and high-performance biomedical devices and healthcare products could be developed with broad long-term benefits to society.

Details

Authors
  • Wei Zhu
  • Sang Hyun Pyo
  • Pengrui Wang
  • Shangting You
  • Claire Yu
  • Jeffrey Alido
  • Justin Liu
  • Yew Leong
  • Shaochen Chen
Organisations
External organisations
  • University of California, San Diego
Research areas and keywords

Subject classification (UKÄ) – MANDATORY

  • Medical Materials

Keywords

  • 3D printing, biomedical devices, bisphenol A-free polycarbonate, BPA, continuous 3D projection printing, healthcare products, photopolymerization, two-photon laser direct writing
Original languageEnglish
Pages (from-to)5331-5339
Number of pages9
JournalACS Applied Materials and Interfaces
Volume10
Issue number6
Publication statusPublished - 2018 Feb 14
Publication categoryResearch
Peer-reviewedYes