Unusual C-H bond activation-aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster

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Abstract

Reactions of the triosmium cluster [HOs3(CO)(10)(eta(1):eta(1)-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C=O moiety to give typical aldol condensation products.

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Subject classification (UKÄ) – MANDATORY

  • Atom and Molecular Physics and Optics
Original languageEnglish
Pages (from-to)827-828
JournalJournal of the Chemical Society. Dalton Transactions
Issue number6
Publication statusPublished - 2002
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)