Vanadia Catalysts on Anatase, Rutile, and TiO2(B) for the Ammoxidation of Toluene: An ESR and High-Resolution Electron Microscopy Characterization

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Vanadia Catalysts on Anatase, Rutile, and TiO2(B) for the Ammoxidation of Toluene: An ESR and High-Resolution Electron Microscopy Characterization. / Sanati, Mehri; Wallenberg, Reine; Andersson, Arne; Jansen, Susan; Tu, Yanping.

In: Journal of Catalysis, Vol. 132, No. 1, 1991, p. 128-144.

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TY - JOUR

T1 - Vanadia Catalysts on Anatase, Rutile, and TiO2(B) for the Ammoxidation of Toluene: An ESR and High-Resolution Electron Microscopy Characterization

AU - Sanati, Mehri

AU - Wallenberg, Reine

AU - Andersson, Arne

AU - Jansen, Susan

AU - Tu, Yanping

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Engineering (011001014), Polymer and Materials Chemistry (LTH) (011001041), Ergonomics and Aerosol Technology (011025002)

PY - 1991

Y1 - 1991

N2 - Three titania polymorphs, anatase, rutile, and TiO2(B), were used as supports for vanadia. Catalysts with nominal loadings corresponding to 1.5 and 5 theoretical layers were prepared. True monolayer samples were obtained by NH3(aq)-treatment of the samples with 5 nominal vanadia layers. Prepared catalysts were characterized by chemical analysis, ESR, and high-resolution electron microscopy. It was observed that an almost complete monolayer of vanadia can be formed on anatase and TiO2(B). The monolayer on TiO2(B) consists of V4+ species. A magnetic species attributable to tetrahedral states of vanadium was found to dominate the ESR resonance. Chemical analysis of the monolayer on anatase showed the presence of both V4+ and V4+ species. The ESR spectrum indicated a high degree of V4+-V4+ interaction. From the characterizations of rutile-supported samples it seems that the support interface is a solid solution of V4+. On all supports, vanadium on top of the monolayer is present as V5+. High-resolution micrographs of the samples with the highest loading revealed the formation of amorphous vanadia on both anatase and rutile. On TiO2(B), vanadia was found to grow coherently at the titania interface. The catalysts were used in the oxidation and ammoxidation of toluene to benzaldehyde and benzonitrile, respectively. Considering both activity and selectivity, multilayers of vanadia supported on TiO2(B) show a good performance for both reactions.

AB - Three titania polymorphs, anatase, rutile, and TiO2(B), were used as supports for vanadia. Catalysts with nominal loadings corresponding to 1.5 and 5 theoretical layers were prepared. True monolayer samples were obtained by NH3(aq)-treatment of the samples with 5 nominal vanadia layers. Prepared catalysts were characterized by chemical analysis, ESR, and high-resolution electron microscopy. It was observed that an almost complete monolayer of vanadia can be formed on anatase and TiO2(B). The monolayer on TiO2(B) consists of V4+ species. A magnetic species attributable to tetrahedral states of vanadium was found to dominate the ESR resonance. Chemical analysis of the monolayer on anatase showed the presence of both V4+ and V4+ species. The ESR spectrum indicated a high degree of V4+-V4+ interaction. From the characterizations of rutile-supported samples it seems that the support interface is a solid solution of V4+. On all supports, vanadium on top of the monolayer is present as V5+. High-resolution micrographs of the samples with the highest loading revealed the formation of amorphous vanadia on both anatase and rutile. On TiO2(B), vanadia was found to grow coherently at the titania interface. The catalysts were used in the oxidation and ammoxidation of toluene to benzaldehyde and benzonitrile, respectively. Considering both activity and selectivity, multilayers of vanadia supported on TiO2(B) show a good performance for both reactions.

U2 - 10.1016/0021-9517(91)90253-Z

DO - 10.1016/0021-9517(91)90253-Z

M3 - Article

VL - 132

SP - 128

EP - 144

JO - Journal of Catalysis

JF - Journal of Catalysis

SN - 1090-2694

IS - 1

ER -