Water-Responsive Internally Structured Polymer Surfactant Films on Solid Surfaces

Research output: Contribution to journalArticle

Abstract

Water-insoluble films of oppositely charged polyionsurfactant ion complex salts (CS) are readily cast on solid surfaces from ethanolic solutions. The methodology introduces new possibilities to study and utilize more or less hydrated CS. Direct SAXS measurements show that the surface films are water-responsive and change their liquid crystalline structure in response to changes in the water activity of the environment. In addition to the classical micellar cubic and hexagonal phases, a rectangular ribbon phase and a hexagonal close-packed structure have now been detected for CS composed of cationic alkyltrimethylammonium surfactants with polyacrylate counterions. Added cosurfactants, decanol or the nonionic surfactant C12E5, yield additional lamellar and bicontinuous cubic structures. Images of the surfaces by optical and atomic force microscopy show that the films cover the surfaces well but have a more or less irregular surface topology, including craters of sizes ranging from a few to hundreds of micrometers. The results indicate possibilities to create a wealth of water-responsive structured CS films on solid surfaces.

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Subject classification (UKÄ) – MANDATORY

  • Theoretical Chemistry
  • Physical Chemistry
Original languageEnglish
Pages (from-to)12525-12531
JournalLangmuir
Volume30
Issue number42
Publication statusPublished - 2014
Publication categoryResearch
Peer-reviewedYes

Bibliographic note

The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039), Physical Chemistry 1 (S) (011001006)