{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskrift

Abstract

The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

Detaljer

Författare
  • Lara C. Spencer
  • Haris Bjelosevic
  • James Darkwa
  • Sofi Elmroth
  • Tina Persson
Enheter & grupper
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Organisk kemi
  • Biologiska vetenskaper

Nyckelord

Originalspråkengelska
Sidor (från-till)M164-U1562
TidskriftActa Crystallographica Section E: Structure Reports Online
Volym64
Utgåva nummer1
StatusPublished - 2008
PublikationskategoriForskning
Peer review utfördJa

Nedladdningar

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Relaterad forskningsoutput

Bjelosevic, H., 2008, Haris Bjelosevic, Organic Chemistry, Lund University. 85 s.

Forskningsoutput: AvhandlingDoktorsavhandling (sammanläggning)

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