A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue

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Abstract

A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.

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Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Organisk kemi
Originalspråkengelska
Sidor (från-till)2019-2022
TidskriftOrganic Letters
Volym7
Utgåva nummer10
StatusPublished - 2005
PublikationskategoriForskning
Peer review utfördJa