A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis
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A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis. / Pyo, Sang Hyun; Park, Ji Hoon; Srebny, Vanessa; Hatti-Kaul, Rajni.
I: Green Chemistry, Vol. 22, Nr. 14, 2020, s. 4450-4455.Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift
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T1 - A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis
AU - Pyo, Sang Hyun
AU - Park, Ji Hoon
AU - Srebny, Vanessa
AU - Hatti-Kaul, Rajni
PY - 2020
Y1 - 2020
N2 - A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is
AB - A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is
U2 - 10.1039/d0gc01454k
DO - 10.1039/d0gc01454k
M3 - Article
AN - SCOPUS:85089067921
VL - 22
SP - 4450
EP - 4455
JO - Green Chemistry
JF - Green Chemistry
SN - 1463-9270
IS - 14
ER -