A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis

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A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis. / Pyo, Sang Hyun; Park, Ji Hoon; Srebny, Vanessa; Hatti-Kaul, Rajni.

I: Green Chemistry, Vol. 22, Nr. 14, 2020, s. 4450-4455.

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskrift

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T1 - A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis

AU - Pyo, Sang Hyun

AU - Park, Ji Hoon

AU - Srebny, Vanessa

AU - Hatti-Kaul, Rajni

PY - 2020

Y1 - 2020

N2 - A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is

AB - A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is

U2 - 10.1039/d0gc01454k

DO - 10.1039/d0gc01454k

M3 - Article

AN - SCOPUS:85089067921

VL - 22

SP - 4450

EP - 4455

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9270

IS - 14

ER -