Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate

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Bibtex

@article{6d0ac6e2d2b5456fa357dd40d1602d54,
title = "Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate",
abstract = "In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.",
author = "Y Xiong and ML Tong and TC An and Hans Karlsson",
year = "2001",
doi = "10.1107/S0108270101015116",
language = "English",
volume = "57",
pages = "1385--1387",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",

}