Benefiting from Spontaneously Generated 2D/3D Bulk-Heterojunctions in Ruddlesden−Popper Perovskite by Incorporation of S-Bearing Spacer Cation

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2D Ruddlesden–Popper (RP) perovskite solar cells have manifested superior operation durability yet inferior charge transport compared to their 3D counterparts. Integrating 3D phases with 2D RP perovskites presents a compromise to maintain respective advantages of both components. Here, the spontaneous generation of 3D phases embedded in 2D perovskite matrix is demonstrated at room temperature via introducing S-bearing thiophene−2−ethylamine (TEA) as both spacer and stabilizer of inorganic lattices. The resulting 2D/3D bulk heterojunction structures are believed to arise from the compression-induced epitaxial growth of the 3D phase at the grain boundaries of the 2D phase through the Pb−S interaction. The as-prepared 2D TEA perovskites exhibit longer exciton diffusion length and extended charge carrier lifetime than the paradigm 2D phenylethylamine (PEA)-based analogues and hence demonstrate an outstanding power conversion efficiency of 7.20% with significantly increased photocurrent. Dual treatments by NH 4 Cl and dimethyl sulfoxide are further applied to ameliorate the crystallinity and crystal orientation of 2D perovskites. Consequently, TEA-based devices exhibit a stabilized efficiency over 11% with negligible hysteresis and display excellent ambient stability without encapsulation by preserving 80% efficiency after 270 h storage in air with 60 ± 5% relative humidity at 25 °C.


Enheter & grupper
Externa organisationer
  • Fudan University

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Materialkemi


TidskriftAdvanced Science
StatusE-pub ahead of print - 2019 maj 17
Peer review utfördJa