cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

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Bibtex

@article{4c686120e45c40b2b2bb9d3b6b2b9c22,
title = "cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)",
abstract = "The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) {\AA}]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).",
keywords = "platinum compounds, data mining, crystallography",
author = "Christian Hansson and {\AA}ke Oskarsson",
note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)",
year = "2008",
doi = "10.1107/S0108270107061902",
language = "English",
volume = "64",
pages = "M61--M63",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",

}