cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

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cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II). / Hansson, Christian; Oskarsson, Åke.

I: Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 64, 2008, s. M61-M63.

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TY - JOUR

T1 - cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

AU - Hansson, Christian

AU - Oskarsson, Åke

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

PY - 2008

Y1 - 2008

N2 - The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

AB - The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

KW - platinum compounds

KW - data mining

KW - crystallography

U2 - 10.1107/S0108270107061902

DO - 10.1107/S0108270107061902

M3 - Article

VL - 64

SP - M61-M63

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

ER -