Electronic ground state of Ni 2 +

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Electronic ground state of Ni 2 +. / Zamudio-Bayer, V.; Lindblad, R.; Bülow, C.; Leistner, G.; Terasaki, A.; Issendorff, B. V.; Lau, J. T.

I: Journal of Chemical Physics, Vol. 145, Nr. 19, 194302, 21.11.2016.

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskrift

Harvard

Zamudio-Bayer, V, Lindblad, R, Bülow, C, Leistner, G, Terasaki, A, Issendorff, BV & Lau, JT 2016, 'Electronic ground state of Ni 2 +', Journal of Chemical Physics, vol. 145, nr. 19, 194302. https://doi.org/10.1063/1.4967821

APA

Zamudio-Bayer, V., Lindblad, R., Bülow, C., Leistner, G., Terasaki, A., Issendorff, B. V., & Lau, J. T. (2016). Electronic ground state of Ni 2 +. Journal of Chemical Physics, 145(19), [194302]. https://doi.org/10.1063/1.4967821

CBE

Zamudio-Bayer V, Lindblad R, Bülow C, Leistner G, Terasaki A, Issendorff BV, Lau JT. 2016. Electronic ground state of Ni 2 +. Journal of Chemical Physics. 145(19). https://doi.org/10.1063/1.4967821

MLA

Vancouver

Zamudio-Bayer V, Lindblad R, Bülow C, Leistner G, Terasaki A, Issendorff BV et al. Electronic ground state of Ni 2 +. Journal of Chemical Physics. 2016 nov 21;145(19). 194302. https://doi.org/10.1063/1.4967821

Author

Zamudio-Bayer, V. ; Lindblad, R. ; Bülow, C. ; Leistner, G. ; Terasaki, A. ; Issendorff, B. V. ; Lau, J. T. / Electronic ground state of Ni 2 +. I: Journal of Chemical Physics. 2016 ; Vol. 145, Nr. 19.

RIS

TY - JOUR

T1 - Electronic ground state of Ni 2 +

AU - Zamudio-Bayer, V.

AU - Lindblad, R.

AU - Bülow, C.

AU - Leistner, G.

AU - Terasaki, A.

AU - Issendorff, B. V.

AU - Lau, J. T.

PY - 2016/11/21

Y1 - 2016/11/21

N2 - The Φ9/24 ground state of the Ni2+ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of 7.4±0.2 K was reached by buffer gas cooling of the molecular ion. The contribution of the spin dipole operator to the x-ray magnetic circular dichroism spin sum rule amounts to 7Tz=0.17±0.06μB per atom, approximately 11% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of 3d transition metals seem to adopt maximum spin magnetic moments in their electronic ground states.

AB - The Φ9/24 ground state of the Ni2+ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of 7.4±0.2 K was reached by buffer gas cooling of the molecular ion. The contribution of the spin dipole operator to the x-ray magnetic circular dichroism spin sum rule amounts to 7Tz=0.17±0.06μB per atom, approximately 11% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of 3d transition metals seem to adopt maximum spin magnetic moments in their electronic ground states.

UR - http://www.scopus.com/inward/record.url?scp=84996607024&partnerID=8YFLogxK

U2 - 10.1063/1.4967821

DO - 10.1063/1.4967821

M3 - Article

VL - 145

JO - Journal of Chemical Physics

T2 - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 19

M1 - 194302

ER -