Electronically Divergent Triscyclometalated Iridium(III) 2-(1-naphthyl)pyridine Complexes and Their Application in Three-Component Methoxytrifluoromethylation of Styrene

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Abstract

A systematic study of the photophysical and electrochemical properties of triscyclometalated homoleptic iridium(III) complexes based on 2-(1-naphthyl)pyridine (npy) ligands is presented. A systematic investigation of ligand substitution patterns showed an influence on the lifetime of the excited state, with slight changes in the absorption and emission spectral features. Specifically, the emission lifetime of a complex of an npy ligand substituted with a strongly electron-withdrawing trifluoromethyl group was longer than that of the corresponding complex with the electronically nonperturbed ligand (3.7 μs versus 1.5 μ s). Electronically complementary ligands and complexes with orthogonal configurations showed slightly shorter excited state lifetimes compared with unsubstituted npy (1.4-3.0 μs). All complexes displayed reversible or quasireversible redox-couple processes, with the complex of the trifluoromethylated ligand showing the highest ground-state oxidation potential E 1/2 ox [Ir(III)/Ir(IV) = 0.95 V vs. SCE in CH 2 Cl 2 ]. This study showed that these complexes can be used as efficient photoredox catalysts, as demonstrated by their application in a regioselective methoxytrifluoromethylation in which the npy complexes showed equal or better performance compared with the archetypical photo redox catalyst tris[2-phenylpyridinato]iridium(III).

Detaljer

Författare
Enheter & grupper
Externa organisationer
  • Lund University
  • University of Nairobi
  • Göteborgs universitet
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Analytisk kemi
  • Biokatalys och enzymteknik

Nyckelord

Originalspråkengelska
Sidor (från-till)792-798
Antal sidor7
TidskriftSynlett
Volym30
Utgivningsnummer7
StatusPublished - 2019 jan 1
PublikationskategoriForskning
Peer review utfördJa