Enantiotopic Discrimination by Coordination-Desymmetrized meso-Ligands

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskrift

Abstract

The first examples of enantiopure catalysts that are chiral merely due to coordination of different metal ions at enantiotopic positions of an achiral meso-ligand are reported. These catalysts exhibit a pseudo-Cs symmetry and are able to catalyze reactions demanding simultaneous involvement of two catalytic sites. The latter was demonstrated by application in the asymmetric ring-opening of meso-epoxides.

Detaljer

Författare
Enheter & grupper
Externa organisationer
  • University of Stavanger
  • Lund University
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Biokatalys och enzymteknik

Nyckelord

Originalspråkengelska
Sidor (från-till)1575-1579
Antal sidor5
TidskriftChemCatChem
Volym12
Utgåva nummer6
StatusPublished - 2020
PublikationskategoriForskning
Peer review utfördJa