Experimental investigation of the Rb-85(2) a (3)Sigma(+)(u) triplet ground state: Multiparameter Morse long range potential analysis

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Abstract

Using perturbation facilitated infrared-infrared double resonance excitation of the Rb-85(2) molecule, we have observed spectrally resolved fluorescence to the a (3)Sigma(+)(u) state. We have analyzed the rovibrational energy level structure of the Rb-85(2) a (3)Sigma(+)(u) state and derived a multiparameter Morse Long Range (MLR) potential and molecular constants for this state, which can be used to predict term values without needing to solve the radial Schroumldinger equation.

Detaljer

Författare
  • Bediha Beser
  • V. B. Sovkov
  • J. Bai
  • E. H. Ahmed
  • C. C. Tsai
  • F. Xie
  • Li Li
  • V. S. Ivanov
  • Marjatta Lyyra
Enheter & grupper
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Atom- och molekylfysik och optik

Nyckelord

Originalspråkengelska
TidskriftJournal of Chemical Physics
Volym131
Utgivningsnummer9
StatusPublished - 2009
PublikationskategoriForskning
Peer review utfördJa