Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol

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Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals : A Key Contributor to Atmospheric Aerosol. / Bianchi, Federico; Kurtén, Theo; Riva, Matthieu; Mohr, Claudia; Rissanen, Matti P.; Roldin, Pontus; Berndt, Torsten; Crounse, John D.; Wennberg, Paul O.; Mentel, Thomas F.; Wildt, Jürgen; Junninen, Heikki; Jokinen, Tuija; Kulmala, Markku; Worsnop, Douglas R.; Thornton, Joel A.; Donahue, Neil; Kjaergaard, Henrik G.; Ehn, Mikael.

I: Chemical Reviews, Vol. 119, Nr. 6, 2019, s. 3472-3509.

Forskningsoutput: TidskriftsbidragÖversiktsartikel

Harvard

Bianchi, F, Kurtén, T, Riva, M, Mohr, C, Rissanen, MP, Roldin, P, Berndt, T, Crounse, JD, Wennberg, PO, Mentel, TF, Wildt, J, Junninen, H, Jokinen, T, Kulmala, M, Worsnop, DR, Thornton, JA, Donahue, N, Kjaergaard, HG & Ehn, M 2019, 'Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol', Chemical Reviews, vol. 119, nr. 6, s. 3472-3509. https://doi.org/10.1021/acs.chemrev.8b00395

APA

CBE

Bianchi F, Kurtén T, Riva M, Mohr C, Rissanen MP, Roldin P, Berndt T, Crounse JD, Wennberg PO, Mentel TF, Wildt J, Junninen H, Jokinen T, Kulmala M, Worsnop DR, Thornton JA, Donahue N, Kjaergaard HG, Ehn M. 2019. Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol. Chemical Reviews. 119(6):3472-3509. https://doi.org/10.1021/acs.chemrev.8b00395

MLA

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Author

Bianchi, Federico ; Kurtén, Theo ; Riva, Matthieu ; Mohr, Claudia ; Rissanen, Matti P. ; Roldin, Pontus ; Berndt, Torsten ; Crounse, John D. ; Wennberg, Paul O. ; Mentel, Thomas F. ; Wildt, Jürgen ; Junninen, Heikki ; Jokinen, Tuija ; Kulmala, Markku ; Worsnop, Douglas R. ; Thornton, Joel A. ; Donahue, Neil ; Kjaergaard, Henrik G. ; Ehn, Mikael. / Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals : A Key Contributor to Atmospheric Aerosol. I: Chemical Reviews. 2019 ; Vol. 119, Nr. 6. s. 3472-3509.

RIS

TY - JOUR

T1 - Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals

T2 - A Key Contributor to Atmospheric Aerosol

AU - Bianchi, Federico

AU - Kurtén, Theo

AU - Riva, Matthieu

AU - Mohr, Claudia

AU - Rissanen, Matti P.

AU - Roldin, Pontus

AU - Berndt, Torsten

AU - Crounse, John D.

AU - Wennberg, Paul O.

AU - Mentel, Thomas F.

AU - Wildt, Jürgen

AU - Junninen, Heikki

AU - Jokinen, Tuija

AU - Kulmala, Markku

AU - Worsnop, Douglas R.

AU - Thornton, Joel A.

AU - Donahue, Neil

AU - Kjaergaard, Henrik G.

AU - Ehn, Mikael

PY - 2019

Y1 - 2019

N2 - Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on pre-existing particles and can be involved in new particle formation. HOM thus contribute to the formation of secondary organic aerosol (SOA), a significant and ubiquitous component of atmospheric aerosol known to affect the Earth's radiation balance. HOM were discovered only very recently, but the interest in these compounds has grown rapidly. In this Review, we define HOM and describe the currently available techniques for their identification/quantification, followed by a summary of the current knowledge on their formation mechanisms and physicochemical properties. A main aim is to provide a common frame for the currently quite fragmented literature on HOM studies. Finally, we highlight the existing gaps in our understanding and suggest directions for future HOM research.

AB - Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on pre-existing particles and can be involved in new particle formation. HOM thus contribute to the formation of secondary organic aerosol (SOA), a significant and ubiquitous component of atmospheric aerosol known to affect the Earth's radiation balance. HOM were discovered only very recently, but the interest in these compounds has grown rapidly. In this Review, we define HOM and describe the currently available techniques for their identification/quantification, followed by a summary of the current knowledge on their formation mechanisms and physicochemical properties. A main aim is to provide a common frame for the currently quite fragmented literature on HOM studies. Finally, we highlight the existing gaps in our understanding and suggest directions for future HOM research.

U2 - 10.1021/acs.chemrev.8b00395

DO - 10.1021/acs.chemrev.8b00395

M3 - Review article

VL - 119

SP - 3472

EP - 3509

JO - Chemical Reviews

JF - Chemical Reviews

SN - 1520-6890

IS - 6

ER -