Interface instabilities of growing hydrides

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Formation of metal hydrides is a serious complication that occur when hydride forming metals such as zirconium, niobium, vanadium and magnesium are exposed to long term hydrogen environment. The main concern is that the hydride, as being a brittle material, has very poor fracture mechanical properties. Formation of hydride is associated with transportation of hydrogen along the gradients of increasing hydrostatic stress, which leads to crack tips and other stress concentrators, where it forms the hydride. In the present study the thermodynamics of the evolving hydrides is studied. The process is driven by the release of free strain, chemical, and gradient energies. A phase field model is used to capture the driving forces that the release of the free energy causes. The study gives the conditions that lead to hydride advancement versus retreat and under which conditions the metal-hydride interface becomes unstable and develops a waviness. The spatial frequency spectrum leading to instability is found to depend on the ratio of the elastic strain energy density and parameters related to the interface energy.


Enheter & grupper
Externa organisationer
  • Blekinge Institute of Technology

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Matematik
  • Fysik
  • Den kondenserade materiens fysik


  • Interface, instability, hydrides, Precipitate growth
Sidor (från-till)589-596
Antal sidor7
TidskriftProcedia Structural Integrity
StatusPublished - 2016 dec 31
Peer review utfördJa
Evenemang21st European Conference on Fracture, ECF 2016 - Catania, Italien
Varaktighet: 2016 jun 202016 jun 24
Konferensnummer: 21