Microscopic insight into the reversibility of photodegradation in MAPbI3 thin films

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Abstract

Whether optoelectronic devices based on metal-halide perovskite semiconductors will become a commercially viable technology will be determined by their intrinsic and operational stability. Recent results indicate there is some reversibility of perovskite degradation in thin films and devices, although mechanistic insight into the processes driving degradation and recovery are still scarce. We here present a comparative spectroscopic study of methylammonium lead iodide (MAPbI3) films having undergone either photo- or thermal degradation under controlled conditions. We confirm that the degradation mechanism pertaining to each type of stress is inherently different. Our results from photoluminescence microscopy measurements paint a spatially, spectrally and temporarily resolved picture showing that, unlike thermally degraded samples, photodegraded samples are in a state that intermittently recovers to luminescent MAPbI3 upon laser excitation. This indicates that rather than irreversibly decomposing, photoinduced degradation leaves MAPbI3 structurally or compositionally intact but induces defects causing non-radiative recombination losses.

Detaljer

Författare
Enheter & grupper
Externa organisationer
  • Helmholtz-Zentrum Berlin for Materials and Energy
  • Skolkovo Institute of Science and Technology
  • Institute of Problems of Chemical Physics
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Fysikalisk kemi
Originalspråkengelska
Artikelnummer116916
TidskriftJournal of Luminescence
Volym219
StatusPublished - 2020
PublikationskategoriForskning
Peer review utfördJa